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Sains Malaysiana 54(5)(2025): 1427-1437
http://doi.org/10.17576/jsm-2025-5405-18
Superconducting
Transition in YBCO Bulk Ceramics: Correlating Sintering Temperature, Phase
Formation, and AC Susceptibility
(Peralihan Superkonduktor dalam Seramik Pukal YBCO: Menghubungkaitkan Suhu Pensinteran, Pembentukan Fasa dan Kecenderungan AC)
RYAD ALHADEI MOHAMED AREBAT1,2, MOHD
MUSTAFA AWANG KECHIK1,*, CHEN SOO KIEN1,
LIM KEAN PAH1, HOO KEONG PEH1 & ABDUL HALIM SHAARI1
1Superconductor & Thin Films
Laboratory, Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
2Department of Physics, Faculty of
Science, El-Mergib University, Al Khums City, Libya
Diserahkan: 10 Oktober 2024/Diterima: 16 Disember 2024
Abstract
Sintering significantly influences the phase composition and crystal
structure of high-temperature superconductors, such as yttrium barium copper
oxide (YBa2Cu3O7-δ, YBCO) bulk ceramics,
thereby impacting their superconductivity. This study investigates the effects of various sintering temperatures
(920 °C, 950 °C, and 980 °C) on phase formation, AC susceptibility, and the
superconducting transition temperature (Tc) in pure YBCO bulk
ceramics synthesized via traditional solid-state reaction method (SSR).
Characterization techniques employed include X-ray diffraction (XRD), AC
susceptibility (ACS), and temperature-dependent resistance measurements via the
four-point probe method (4PP). XRD
analysis confirmed the predominance of the YBCO phase across all samples, with
the highest phase purity (98.9%) and optimal oxygen content achieved at 980 °C.
The superconducting transition temperature Tc-onset measured
by ACS for the sample sintered at 980 °C was 93.21 K, while 4PP yielded a Tc-onset of 91.28 K; both values decreased at lower sintering temperatures. Notably, the
superconducting transition width (ΔTc)
narrowed with increasing sintering temperature, with the sharpest transition observed
at 980 °C, indicating enhanced phase homogeneity and intergranular
connectivity. Additionally, the critical current density (Jcm)
at the peak temperature (Tp) of the
imaginary part (χ'') was calculated using the Bean critical state model,
revealing a maximum Jcm of 7.639
A/cm² for the sample sintered at 980 °C.
Keywords: AC susceptibility
(ACS); sintering temperature; superconducting transition temperature (Tc);
X-ray diffraction (XRD); YBCO bulk ceramic
Abstrak
Pensinteran memberi pengaruh yang ketara terhadap komposisi fasa dan struktur kristal bagi pengalir super suhu tinggi, seperti seramik pukal oksida kuprum barium itrium (YBa2Cu3O7-δ,
YBCO) yang seterusnya mempengaruhi kekonduksian super mereka. Penyelidikan ini mengkaji kesan pelbagai suhu pensinteran (920 °C, 950 °C dan 980 °C) terhadap pembentukan fasa, kepekaan AC dan suhu peralihan kekonduksian super (Tc) dalam seramik pukal YBCO tulen yang disintesis melalui kaedah tindak balas pepejal (SSR). Teknik pencirian yang
digunakan termasuk pembelauan sinar-X (XRD), kepekaan AC (ACS) dan pengukuran
rintangan bergantung suhu melalui kaedah penduga empat titik (4PP). Analisis XRD mengesahkan dominasi fasa YBCO
dalam semua sampel dengan ketulenan fasa tertinggi (98.9%) dan kandungan
oksigen yang optimal dicapai pada suhu 980 °C. Suhu peralihan kekonduksian
super Tc-onset yang diukur oleh ACS untuk sampel yang
disinter pada 980 °C adalah 93.21 K, manakala 4PP menunjukkan Tc-onset sebanyak 91.28 K; kedua-dua nilai tersebut menurun pada suhu pensinteran
yang lebih rendah. Secara ketara, lebar peralihan kekonduksian super (ΔTc) menyempit dengan
peningkatan suhu pensinteran, dengan peralihan yang paling tajam diperhatikan
pada 980 °C, menunjukkan peningkatan homogeniti fasa dan kehubungan antara
butir. Tambahan pula, ketumpatan arus kritikal (Jcm) pada suhu puncak (Tp)
bahagian imajiner (χ'') telah dikira
menggunakan model keadaan kritikal Bean, mendedahkan Jcm maksimum sebanyak
7.639 A/cm² untuk sampel yang disinter pada 980 °C.
Kata kunci: Kepekaan AC (ACS); pendifraksian sinar-X (XRD); seramik pukal
YBCO; suhu pensinteran; suhu peralihan kekonduksian super (Tc)
RUJUKAN
Abdul
Hussein, A.A., Abdul Hussein, A.M. & Hasan, N.A. 2023. Study of the properties
of YBCO superconductor compound in various preparation methods: A short review. Journal
of Applied Sciences and Nanotechnology 3(1): 65-79. https://www.iasj.net/iasj/download/fb012650d9a005d5
Aima Ramli, Abdul Halim Shaari, Chen Soo Kean & Mohd
Mustafa Awang Kechik. 2018. The effect of Sm2O3 nanoparticle inclusion on superconducting properties of YBCO ceramics. ASM
Sci. J. Special Issue 2018(1): 9-16. https://doi.org/10.1016/S1002-0721(16)60112-6
Aima Ramli, Abdul Halim Shaari, Hussein Baqiah, Chen Soo
Kean, Mohd Mustafa Awang Kechik & Zainal Abidin Talib. 2016. Role of Nd2O3 nanoparticles addition on microstructural and superconducting properties of YBa2Cu3O7-δ ceramics. Journal of Rare Earths 34(9): 895-900.
Aşikuzun, E. & Öztürk, Ö. 2020. Theoretical and experimental
comparison of micro-hardness and bulk modulus of orthorhombic YBa2Cu3-xZnxO
superconductor nanoparticles manufactured using sol-gel method. Sakarya
University Journal of Science 24(5): 854-864. https://doi.org/10.16984/saufenbilder.676028
Bahboh, A., Shaari, A.H., Baqiah, H., Chen, S.K., Awang
Kechik, M.M., Talib, Z.A. & Dihom, M.M. 2019. Effect of sol-gel synthesized
BiFeO3 nanoparticle addition in YBa2Cu3O7–δ (Y123) superconductor synthesized by standard solid state reaction method. Solid State Phenomena 290: 245-251. https://www.scientific.net/SSP.290.245
Barood, F., Awang Kechik, M.M., Tee, T.S., Kien, C.S., Pah, L.K.,
Hong, K.J., Shaari, A.H., Baqiah, H., Abdul Karim, M.K. & Shabdin, M.K. 2023.
Orthorhombic YBa2Cu3O7–δ superconductor
with TiO2 nanoparticle addition: Crystal structure, electric
resistivity, and AC susceptibility. Coatings 13(6): 1093. https://doi.org/10.3390/coatings13061093
Bartůněk, V., Luxa, J., Sedmidubský, D., Hlásek, T.
& Jankovský, O. 2019. Microscale and nanoscale pinning centres in
single-domain REBCO superconductors. Journal of Materials Chemistry C 7(42): 13010-13019. https://pubs.rsc.org/en/content/articlehtml/2019/tc/c9tc01455a
Bean, C.P. 1962. Magnetization of hard superconductors. Physical Review Letters 8(6): 250.
Benzi, P., Bottizzo, E. & Rizzi, N. 2004. Oxygen
determination from cell dimensions in YBCO superconductors. Journal of Crystal Growth 269(2-4): 625-629. https://doi.org/10.1016/j.jcrysgro.2004.05.082
Campi, G., Ricci, A., Poccia, N. & Bianconi, A. 2014.
Imaging spatial ordering of the oxygen chains in YBa2Cu3O6+y at the insulator-to-metal transition. Journal
of Superconductivity and Novel Magnetism 27: 987-990. https://doi.org/10.1007/s10948-013-2434-7
Chen, X., Yang, S., Chen, Y., Wang, L., Zhang, Y., Feng, Y.
& Zhao, Y. 2022. Phase formation and superconductivity of Nb3Al bulk
materials prepared by spark plasma sintering and powder metallurgy. Journal of Superconductivity and Novel
Magnetism 35(9): 2339-2347. https://doi.org/10.1007/s10948-022-06271-z
Cheong, C.M. & Chen, S.K. 2024. Characterization of YBa2Cu4O8 superconductor prepared by using YBa2Cu3O7-x
and CuO via solid state reaction technique with heating under ordinary oxygen
pressure. Materials Today: Proceedings 96: 50-54. https://doi.org/10.1016/j.matpr.2023.09.212
Chin, T.S., Huang, T.W., Lin, W.T., Wu, N.C., Chou, Y.H., Wu,
T.C., Wu, P.T. & Yen, H.H. 1987. The formation of Y-Ba-Cu-O phases during
solid state reaction. MRS Online
Proceedings Library 99: 261-264. https://doi.org/10.1557/PROC-99-261
Deac, I.G., Burzo, E., Pop, A.V., Pop, V., Tetean, R., Kovacs,
D. & Borodi, G. 1999. Intergranular properties of (Y1-xy ZrxCay)Ba2Cu3O7-δ compounds. International Journal of
Modern Physics B 13(13): 1645-1654. https://doi.org/10.1142/S0217979299001624
Dubinsky, S., Lumelsky, Y., Grader, G.S., Shter, G.E. &
Silverstein, M.S. 2005. Thermal degradation of poly(acrylic acid) containing
metal nitrates and the formation of YBa2Cu3O7−X. Journal of Polymer Science Part B:
Polymer Physics 43(10): 1168-1176.
Farneth, W.E., Bordia, R.K., McCarron III, E.M., Crawford, M.K.
& Flippen, R.B. 1988. Influence of oxygen stoichiometry on the structure
and superconducting transition temperature of YBa2Cu3Ox. Solid State Communications 66(9): 953-959. https://doi.org/10.1016/0038-1098(88)90545-5
Hannachi, E., Mahmoud, K.A., Sayyed, M.I. & Slimani, Y. 2022.
Effect of sintering conditions on the radiation shielding characteristics of
YBCO superconducting ceramics. Journal of
Physics and Chemistry of Solids 164: 110627
Hong, S., Kim, R.S., Qi, Y., Zhao, X., Kim, S.H. & Ryu, Y.G.
2023. Thermal decomposition of precursor of YBa2Cu3O7-δ superconducting layer. Reaction Kinetics,
Mechanisms and Catalysis 136(5): 2801-2813. doi: https://doi.org/10.1007/s11144-023-02486-w
Howe, B.A. 2014. Crystal
Structure and Superconductivity of YBa2Cu3O7-x.
Mankato: Minnesota State University.
Jin, F., Zhang, H., Wang, W., Liu, X. & Chen, Q. 2017.
Improvement in structure and superconductivity of YBa2Cu3O6+y+δ ceramics superconductors by optimizing sintering processing. Journal of Rare Earths 35(1): 85-89. https://doi.org/10.1016/S1002-0721(16)60177-1
Kamarudin, A.N., Awang Kechik, M.M., Abdullah, S.N., Baqiah, H.,
Chen, S.K., Abdul Karim, M.K., Ramli, A., Lim, K.P., Shaari, A.H. & Miryala,
M. 2022. Effect of graphene nanoparticles addition on superconductivity of YBa2Cu3O7~
δ synthesized via the thermal treatment method. Coatings 12(1): 91. https://www.mdpi.com/2079-6412/12/1/91
Kameli, P., Salamati, H. & Abdolhosseini, I. 2008. AC
susceptibility study of Bi1. 66Pb0. 34Sr2Ca2−
xMgxCu3Oy (x= 0, 0.2 and 0.4) superconductor systems. Journal of Alloys and Compounds 458(1-2): 61-65.
Koblischka-Veneva, A., Koblischka, M.R., Berger, K., Nouailhetas,
Q., Douine, B., Muralidhar, M. & Murakami, M. 2019. Comparison of temperature
and field dependencies of the critical current densities of bulk YBCO, MgB2,
and iron-based superconductors. IEEE Transactions on Applied
Superconductivity 29(5): 1-5 https://ieeexplore.ieee.org/abstract/document/8649756
Kulpa, A., Chaklader, A.C.D., Osborne, N.R., Roemer, G., Sullivan,
B. & Williams, D.Ll. 1989. Influence of oxygen ordering and sintering
temperatures on the superconducting transition temperature of YBa2Cu3Ox
compound at fixed oxygen content x higher than x= 6.8. Solid State Communications 71(4): 265-268. https://doi.org/10.1016/0038-1098(89)91011-9
Mohammad Rasti & Mohammad Reza Mohammadizadeh. 2020.
Fabrication of YBCO thin films by fluorine-free MOCSD method: Influence of
sintering near the melting point. IEEE
Transactions on Applied Superconductivity 30(6): 1-8. https://ieeexplore.ieee.org/abstract/document/9050541
Mustafa Mousa Dihom, Abdul Halim Shaari, Hussein Baqiah, Naif
Mohammed Al-Hada, Chen, Soo Kean, Rabaah Syahidah Azis, Mohd Mustafa Awang
Kechik & R. Abd-Shukor. 2017. Effects of calcination temperature on
microstructure and superconducting properties of Y123 ceramic prepared using
thermal treatment method. Solid State
Phenomena 268: 325-329. https://www.scientific.net/SSP.268.325
Nazarudin, M.F., Hamadneh, I., Tan, W.T. & Zainal, Z. 2011.
The effect of sintering temperature variation on the superconducting properties
of ErBa2Cu3O7−δ superconductor
prepared via coprecipitation method. Journal
of Superconductivity and Novel Magnetism 24: 1745-1750.
Nur-Akasyah, J., Abd-Shukor, R. & Chong, T.V. 2023.
Elemental substitution at Tl site of Tl1− xXx (Ba, Sr) CaCu2O7 superconductor with X= Cr, Bi, Pb, Se, and Te. Materials 16(11): 4022. https://doi.org/10.1016/j.ceramint.2021.08.078
Nur-Akasyah, J., Ranjbar, M.G. & Abd-Shukor, R. 2021.
Influence of Se and Te substitutions at Tl-site of Tl (Ba, Sr) CaCu2O7 superconductor on the AC susceptibility and electrical properties. Ceramics International 47(22):
31920-31926.
Nurhidayah Mohd Hapipi, Soo Kien Chen, Abdul Halim Shaari,
Mohd Mustafa Awang Kechik, Kar Ban Tan & Kean Pah Lim. 2018.
Superconductivity of Y2O3 and BaZrO3 nanoparticles co-added YBa2Cu3O7−δ bulks prepared using co-precipitation method. Journal of Materials Science:
Materials in Electronics 29(21): 18684-18692. doi:
10.1007/s10854-018-9991-2
Nurhidayah Mohd Hapipi, Abdul Halim Shaari, Mohd Mustafa
Awang Kechik, Kar Ban Tan, Roslan Abd-Shukor, Nurul Raihan Mohd Suib & Soo
Kien Chen. 2017. Effect of heat treatment condition on the phase formation of
YBa2Cu3O7-δ superconductor. Solid State Phenomena 268: 305-310. https://www.scientific.net/ssp.268.305
Nur Afiqah Mohamed Indera Alim Sah, Mohd Mustafa Awang
Kechik, Chen Soo Kien, Lim Kean Pah, Abdul Halim Shaari, Muhammad Kashfi
Shabdin, Muhammad Khalis Abdul Karim, Muralidhar Miryala, Hussein Baqiah,
Khairul Khaizi Mohd Shariff, Yap Siew Hong & Arebat Ryad Alhadei Mohamed.
2024. Comparative studies of pure YBa2Cu3O7-ẟ prepared by modified thermal decomposition method against thermal treatment
method. Applied Physics A 130(5): 340. doi:
10.1007/s00339-024-07412-y
Nur Athirah Che Dzul-Kifli, Mohd Mustafa Awang Kechik,
Hussein Baqiah, Abdul Halim Shaari, Kean Pah Lim, Soo Kien Chen, Safia Izzati
Abd Sukor, Muhammad Kashfi Shabdin, Muhammad Khalis Abdul Karim, Khairul Khaizi
Mohd Shariff & Muralidhar Miryala. 2022. Superconducting properties of YBa2Cu3O7−δ with a multiferroic addition synthesized by a capping agent-aided thermal
treatment method. Nanomaterials 12(22): 3958. https://doi.org/10.3390/nano12223958
Nur Nabilah Mohd Yusuf, Mohd Mustafa Awang Kechik, Hussein
Baqiah, Chen Soo Kien, Lim Kean Pah, Abdul Halim Shaari, Wan Nur Wathiq Wan
Jusoh, Safia Izzati Abd Sukor, Mustafa Mousa Dihom & Zainal Abidin Talib.
2018. Structural and superconducting properties of thermal
treatment-synthesised bulk YBa2Cu3O7−δ superconductor: Effect of addition of SnO2 nanoparticles. Materials 12(1): 92. https://doi.org/10.3390/ma12010092
Ozturk, O., Arebat, R.A.M., Nefrow, A.R.A., Bulut, F., Guducu,
G., Asikuzun, E. & Celik, S. 2019. Investigation of structural,
superconducting and mechanical properties of Co/Cu substituted YBCO-358 ceramic
composites. Journal of Materials Science:
Materials in Electronics 30(8): 7400-7409. doi:
10.1007/s10854-019-01053-1
Pathak, L.C., Mishra, S.K., Das, S.K., Bhattacharya, D. &
Chopra, K.L. 2001. Effect of sintering atmosphere on the weak-link behaviour of
YBCO superconductors. Physica C:
Superconductivity 351(3): 295-300. https://doi.org/10.1016/S0921-4534(00)01628-2
Poonam, R., Jha, R. & Awana, V.P.S. 2013. AC
susceptibility study of superconducting YBa2Cu3O7:
Agx bulk composites (x= 0.0–0.20): The role of intra and
intergranular coupling. Journal of
Superconductivity and Novel Magnetism 26: 2347-2352. https://doi.org/10.1007/s10948-013-2203-7
Pruss, N., Kraak, W., Müller, H‐U., Jacobi, A., Dwelk, H.
& Herrmann, R. 1989. Influence of the sintering temperature on the physical
properties of YBa2Cu3O7−δ ceramic
samples. Physica Status Solidi (a) 116(2): 793-801. https://doi.org/10.1002/pssa.2211160240
Reissner, M., Steiner, W., Stroh, R., Hörhager, S., Schmid, W.
& Wruss, W. 1990. Influence of sintering temperature on the superconducting
properties of YBa2Cu3O7-x. Physica C: Superconductivity 167(5-6): 495-502. https://doi.org/10.1016/0921-4534(90)90665-2
Ryad Alhadei Mohamed Arebat, Mohd Mustafa Awang Kechik, Chen
Soo Kien, Lim Kean Pah, Hussien Baqiah, Khairul Khaizi Mohd Shariff, Abdul
Halim Shaari, Muralidhar Miryala, Yap Siew Hong & Nur Afiqah Indera Mohamed
Indera Alim Sah. 2024a. YBa2Cu3O7-d bulk
superconductors: Exploring the impact of two synthesis techniques on the
microstructure and critical temperature. Solid
State Science and Technology 32(2):
28-41. https://myjms.mohe.gov.my/index.php/masshp/article/view/25985
Ryad Alhadei Mohamed Arebat, Mohd Mustafa Awang Kechik, Chen
Soo Kien, Lim Kean Pah, Hussien Baqiah, Khairul Khaizi Mohd Shariff, Yap Siew
Hong, Hoo Keong Peh, Abdul Halim Shaari, Syahrul Humaidi & Muralidhar
Miryala. 2024b. Enhancing superconducting properties of YBa2Cu3O7-ẟ through Nd2O3 addition prepared using modified thermal
decomposition method. Applied Physics A 130(12): 897. doi: 10.1007/s00339-024-08035-z
Yap Siew Hong, Mohd Mustafa Awang Kechik, Hussien Baqiah, Soo
Kien Chen, Kean Pah Lim, Muhammad Kashfi Shabdin, Mohd Hafiz Mohd Zaid, Yazid
Yaakob, Mohd Khalis Abdul Karim, Zhi Wei Loh, Abdul Halim Shaari &
Muralidhar Miryala. 2024a. Comparative study of superconducting properties for
YBa2Cu3O7-ẟ added Ca-compounds
synthesized under different annealing conditions. Solid State Science and Technology 31(2): 71-81.
Yap Siew Hong, Mohd Mustafa Awang Kechik, Fitri Khoerunnisa,
Hussien Baqiah, Soo Kien Chen, Kean Pah Lim, Muhammad Kashfi Shabdin, Mohd
Hafiz Mohd Zaid, Yazid Yaakob, Mohd Khalis Abdul Karim, Syahrul Humaidi, Abdul
Halim Shaari & Muralidhar Miryala. 2024b. Microstructural and excess
conductivity properties of Y-123: Effect of organic polymer chitosan inclusion. Journal of Materials Science: Materials
in Electronics 35(21): 1452.
Yap Siew Hong, Mohd Mustafa Awang Kechik, Khairul Khaizi Mohd
Shariff, Hussien Baqiah, Soo Kien Chen, Kean Pah Lim, Muhammad Kashfi Shabdin,
Mohd Hafiz Mohd Zaid, Yazid Yaakob, Mohd Khalis Abdul Karim, Syahrul Humaidi,
Abdul Halim Shaari & Muralidhar Miryala. 2024c. Fluctuation induces
conductivity and microstructural studies in Y-123: Effect of CaO inclusion. Journal of Alloys and Compounds 1005: 175955. https://doi.org/10.1016/j.jallcom.2024.175955
Yeoh, L.M. & Abd-Shukor, R. 2008. The study on various
wet chemistry techniques on YBa2Cu3O7−δ superconducting oxides powder preparation. Journal
of Non-Crystalline Solids 354(34): 4043-4048. https://www.sciencedirect.com/science/article/pii/S0022309308003190
Zhou, M., Sun, A., Sun, L. & Han, P. 2013. Effect of the
oxygen distribution and inhomogeneity on the superconducting properties of YBa2Cu3O7−δ+x
mol% Y2Ba4CuMoOy superconductors. Superconductor Science and Technology 26(10): 105006. https://iopscience.iop.org/article/10.1088/0953-2048/26/10/105006/meta
*Pengarang untuk surat-menyurat; email: mmak@upm.edu.my
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